Anderson型多金屬氧酸鹽與生物分子的自組裝合成、結(jié)構(gòu)與性質(zhì).pdf

1、學(xué)校代碼：2Q墊Q分類號(hào)：避研究生學(xué)號(hào)l—12316—04008密級(jí)：五◎東牡h予葒媳碩士學(xué)位論文Anderson型多金屬氧酸鹽與生物分子的自組裝合成、結(jié)構(gòu)與性質(zhì)SelfassembledSynthesis，StructuresandPropertiesofBiologyMoleculesandPolyoxometalatesofAndersontype作者：王豐指導(dǎo)教師；學(xué)科專業(yè)：研究方向：學(xué)位類型：劉術(shù)俠教授無機(jī)化學(xué)多酸化學(xué)高校教師

2、東北師范大學(xué)學(xué)位評(píng)定委員會(huì)2007年6月AbstractInthispaperSynthesisprocessesoffournewPolyoxometalatessupramolecularcompoundscontainingbiologymolecular，suchasMoroxydine，Hydrochlorideand2amino5fluoro4pyrimidinolectareintroduced，andthreecryst

3、alstructuresofthecompoundareexposedThemolecularformulasofthreecompoundsarelistedasfollowing：1、fCd114N50)2(C61115N50)2[TeM06024]’4H202、(C出15NsO)3[TeW6024]‘10H203、Na3[(C4FN30Hs)3(C4FN30H4)3][TeM06024]’8H20Thethreecorrespon

4、dingcrystalstructureofthisthreecompoundsarereported：fCd114NsO)2(C6H15N50)2[TeM06024]‘4H20：ItcrystallizesinmonocliniccrystalsystemwithspacegroupP2(1)／n，inthisstructure，a=15722(3)A，b=92364(18)A，c=19256(4)A，p=9467(3)。，V=278

5、70(10)A3，F(xiàn)(000)=1820T11eAndersontypeheteropolyanions[TeM06024]扣retaintheirskeletonandtheABOBorganicmoleculesareprotonatedthroughoutthereactionElectrostaticforcesandhydrogenbondinginteractionsbetweenthe[TeM06024]”anions，H

6、20andprotonatedABOBmoleculesresultinitsthreedimensionalsupramolecularstructurefC6Hi5N50)3[TeW6024]。10H20：ItcrystallizesinTricliniccrystalsystemwithspacegroupP1，inthisstructure，a=13073(3)A，b=1315鉞3)A，c=17881(4)A，p=9318(3)

7、o，V26183(9)A3，F(xiàn)(000)=2120Thiscompoundiscomposedofseparated【TeM06024]“，protonatedMoroxydineandlatticewatermoleculesThethreedimensionalsupramolecularstructureisformedbyelectrostaticforcesandhydrogenbondinginteractionsbetwe

8、enthesecomponentsNa3[(C4FN30H5)3(C4FN30H4)3][TeM06024]‘8H20：ItcrystallizesinTricliniccrystalsystemwithspacegroupP1，inthisstructure，a=110691(10)A，b=114899(10)A，c=135807(12)A，B=662530(10)。，V=14334(2)A3，F(xiàn)(000)=98911liscompo

9、undiscomposedofseparated[TeM06024]”，protonatedandnonprotonated2amino5fluoro4pyrimidinol，latticewatermoleculesandNacationThethree—dimensionalsupramolecularstructureisformedbyelectrostaticforcesandhydrogenbondinginteractio

10、nsbetweenthesecomponentsThreecompoundshavebeencharacterizedbyelementanalysis，infraredspectrumandDTATGanalysisKeywords：Polyoxometalate；Tellurium；Namidino4morpholincarboxamidine；2amino5fluoro4pyrimidinol；Anderson；Crystalst