纖維負(fù)載新型鈷酞菁及催化氧化性能研究.pdf

1、Y7“b‘浙江理乒太學(xué)zhejia”gunlversityofscence碩士學(xué)位論文MAsTERTHEs|S埝文題H學(xué)科專、№作者姓名指導(dǎo)教師坤殛靴旦i蛐蹲，’盈硌趔靴地j紐睜』蘭勉到翌老轟盞4監(jiān)虹三璽幺壘鷺?！坏┲爻?愿寸砂船／ABSTRACTPhthaIocyaninesbavemanyexcellentperfbrnlallces，suchasphotoconduction，gas—sensingproperty，cataI

2、yticactiVityandbionicperfomlaIlceforbigconjugatedsystem，soitiswidelyusedinm卸yfieldsInmisp印er，cobaltphtllaloc”ninesoftetracarboxylicacidafldtetra啪ineswercsymhesizedCobalttetm枷inophthalocyanine、相smodifiedbybutanedioicanhyd

3、rideandmaleicanhydriderespectivelytogettwonewtypeaqueouscobaltphthalocyanines右rstlyA11thesepromlctswerecharacterizedbyIR卸delementaryanalyseInthehomogenoussyStem，thecatalyticoxidationactivityofphthalocyaninesformercaptoet

4、hanolanddecomposabil畸ofphthalocyaninesforH202weremeasured，aIldtheeff&tsofpH，time，catalyzerconcentration，substrateconcentrationanddif詫rentph吐1“ocyanineonthecatal”icoxidationactivityanddecomposability、vereinVestigatedThere

5、suhsshowthattwonew母pecobaltphthaJocyaninesshowtIlebestcat“yticoxidationactivityatpH11ThecatalyticoxidationactiVity、vasimproved、vithtl】erisingoftemperaturcThedecomposabilityofphmaIocyallinesforH202wasimprovedwiththerising

6、ofpHAnewkindofmacromoIecularart埔cialenzymecanbeobtainedbycombiningphthalocyaninemoleculesa11dcellulosem01eculesCellulosefibers、vereselectedinthisexperimemTwomemodswereutilizedto10adnewtypephthalocyaniesOntheonehand，these

7、nberswerepretreatedbycationicmodifierSMfirst，andthenwerecarriedphthalocyamneontlleotherhalld，cellulosenberswereinitiatedbymesystemofpotassiumpersulfate，sodiumthiosulphatetoloadphthalocyallineLoadingquantitywasmeasuredbya

8、tomicabsorptionspec仃ometryTheresuhsshowthattWomethodshaVegoodabilitytoloadcobaltphmalocyanines，ThecatalmicoxidationactiV時oft、voloadingph(halocyaninecellulose舶ersformerca口toehtanolanddecomposabmtyofmesefibersforH202wereme